Everything is done on the server....
Server Management....Users...
Go to Properties for the particular user....
Under Exchange Features you can disable web access and mobile access.....
Exchange General-->Delivery Options : You can forward all e-mail to particular account
You can also change the Dial-In settings or just remove the user from all groups under the Member Of tab...
If you need to get e-mail off the computer or files, just change the password so you can get access to the computer.
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